Unexpected Synthesis of a Bulky Bis-Pocket A₃B-Type Meso-Cyano Porphyrin.
نویسندگان
چکیده
A one-pot synthesis of bulky bis-pocket A₃B-type meso-cyano porphyrin, 5-cyano-10,15,20-tris(2,4,6-triphenylphenyl)porphyrin, has been accomplished via trifluoroacetic acid (TFA) catalyzed condensation of pyrrole and 2,4,6-triphenylbenzaldehyde in an acceptable yield of about 4%. DDQ served as oxidant and the cyanating agent.
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عنوان ژورنال:
- Molecules
دوره 22 11 شماره
صفحات -
تاریخ انتشار 2017